First, the goods and manufacturers information
| Item Name: 4-Chlorobenzotrifluoride |
| Other names: / |
| Suggestions for use and usage restrictions: / |
| Supplier name, address: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: 4-Chlorobenzotrifluoride |
| Hazard classification and national or regional information: Product classification: Flammable liquid Category 3 Skin sensitizer Category 1B Hazardous aquatic environment - Long-term hazard category 2 |
GHS label elements, including precautionary statements:    Signal word: Hazardous Hazard Statement: H226 Flammable liquid and vapour. H317 May cause an allergic skin reaction. H411 is toxic to aquatic life with long lasting effects. Prevention : • Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep the container closed. Grounding/equal connection of container and loading equipment. Use explosion-proof electrical / ventilation / lighting / equipment. Use only tools that do not produce sparks. Take measures to prevent electrostatic discharge. Wear protective gloves / protective clothing / eye protection / face protection. Avoid breathing dust/fume/gas/mist/vapor/spray. Contaminated work clothes should not be taken out of the workplace. Avoid release to the environment. Strictly concealed to avoid release into the environment; Reaction : If the skin (or hair) is contaminated: Take off all contaminated clothing immediately. Wash skin / shower with water. • In case of fire: Use a fire extinguisher to extinguish the fire. If the skin is contaminated: Wash thoroughly with water. If skin irritation or rash occurs: Get medical advice/ attention. Specific treatment (see on this label...). Remove contaminated clothing and wash it to collect spillage. Storage : Store in a well-ventilated place. Keep it cool. Disposal : Dispose of contents/container in local regulations. |
Third, the component identification dataPure substances:
| Chemical Name 4-Chlorobenzotrifluoride / |
| Common name: / |
| Chemical Abstracts Service Registration Number (CAS No.): 98-56-6 |
| Hazardous substance composition (percentage of ingredients):> |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, the risk overview:
| Health hazards: Inhalation: If inhaled, move patient to fresh air. Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| Explosion hazard: / |
Fifth, first aid measures
| First aid methods for different exposure routes: |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Get medical attention immediately |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Sixth, fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. |
| Hazardous characteristics: No information available. |
| Hazardous combustion products: / |
| Special fire fighting procedures: / |
| Special protective equipment and precautions for firefighters: Firefighters must wear a gas-filled respirator, wear a full-body fire-fighting suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Seven, leakage treatment method
| Small amount of leakage: Collect leaking liquid as much as possible in a closable container. Absorb with sand, activated carbon or other inert materials and transfer to a safe place. It is forbidden to rush into the sewer. A large number of leaks: building a dike or digging a pit. Close the drain pipe. Cover with foam to inhibit evaporation. Transfer to a tank truck or special collector with an explosion-proof pump, recycle or transport to a waste disposal site for disposal. |
| Environmental precautions: Contain spills to avoid environmental pollution. Prevent spills from entering sewers, surface water and groundwater. |
Eight, handling and storage
| Handling Precautions: Operators should be specially trained to strictly follow the operating procedures. Handling should be carried out in a location with local or full ventilation. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues. Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Storage Precautions: Store in a cool, ventilated warehouse. The temperature should not exceed 37 ° C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat. Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Nine, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation.Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation. |
| Eye protection: Wear chemical safety eye protection. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: / |
X. Physical and chemical properties
| Appearance (physical status, color, etc.) | Transparent liquid |
| odor | no data |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | / |
| Boiling point (°C) | 136-138 °C (lit.) |
| Flash point (°C) | 43 ° C (lit.) |
| Evaporation rate | / |
| Flammability (solid, gaseous) | no data |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| no data | no data |
| Relative density | 1.353 g/mL at 25 °C (lit.) |
| Solubility | 29 ppm (23 oC). |
| Uses | / |
Eleventh, stability and reactivity
| Chemical stability: This product is stable during storage and use at normal ambient temperature. |
| Possibility of hazardous reactions: No information available. |
| Conditions to avoid (such as static unloading, shock or vibration): Electrostatic discharge, heat, humidity, etc. |
| Incompatible materials and materials: / |
| Dangerous decomposition products: / |
Twelveth, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms related to physical, chemical and toxicological characteristics: strong irritant |
| Chronic toxicity or long-term toxic effects: / |
| Quantitative measurement of toxicity (eg acute toxicity estimate): Oral: LD50 Rat oral 13 g/kg (13,000 mg/kg) Inhalation: LC50 Rat inhalation 33 mg/L/4 hr |
Thirteen, Ecological information
| Ecotoxicity: Very toxic to aquatic organisms. |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Fourteen, Disposal methods:
Refer to national and local regulations before disposal. It is recommended to use incineration. After mixing with the fuel, it is incinerated. The hydrogen halide discharged from the incinerator is removed by an acid scrubber.
Fifteen, Transportation information
| Dangerous Goods Code: UN2234 |
| UN number: 1765 |
| UN transport name: CHLOROBENZOTRIFLUORIDES |
| Transport hazard categories: 3 |
| Packing category: III |
| wrapping method: / |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank), the vehicle should have a grounding chain. A hole partition can be installed in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. |
Sixteen, Regulatory information
| Applicable regulations (safety, health and environmental regulations for related products): Component 4-Chlorobenzotrifluoride CAS: 98-56-6 Occupational Disease Prevention Law of the People's Republic of China: Classification of Occupational Disease Hazard Factors (2015): Not listed as hazardous chemical safety Regulations: Catalogue of Dangerous Chemicals (2015): List of Dangerous Chemicals Listed in Explosives (2017): List of Hazardous Chemicals not listed for priority supervision: List of the first and second batch of hazardous chemicals under key supervision: Not included in the Environmental Management Registration Procedure for Hazardous Chemicals (Trial): List of Hazardous Chemicals for Key Environmental Management: Not included in the Regulations on the Administration of Narcotic Drugs and Psychotropic Substances: Catalogue of Narcotic Drugs: Not included in the list of psychotropic substances: Not included in the new Environmental Management Measures for Chemical Substances: List of Existing Chemical Substances in China (2013): |
Seventeenth, Other information
| references | / | |
| Tabulation unit |
Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
