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First, the goods and manufacturers information
| Item Name: Diallylamine Hydrochloride |
| Other names: N-2-propenyl-2-propene-1-amine hydrochloride |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: Diallylamine Hydrochloride |
| Hazard classification and national or regional information: Acute oral toxicity Category 4 Serious eye damage / Eye irritation category 1 |
GHS label elements, including precautionary statements:   Signal word: Hazardous Hazard Statement: H302 Harmful if swallowed. H318 Causes serious eye damage. • Prevention : Precautions: • P264 Wash thoroughly after work. • P270 Do not eat, drink or smoke when using this product. • P280 Wear protective gloves/protective clothing/eye protection/face protection. Reaction : P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor P330 如口 if you feel unwell . P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. If you wear contact lenses and can easily remove them, take out the contact lenses. Continue to rinse. P310 Call the Detoxification Center/Doctor immediately. Storage : / Disposal : P501 Dispose of contents/container in accordance with local regulations. |
Third, the component identification data Pure substances:
| Chemical name: Diallylamine Hydrochloride / |
| Common name: / |
| Chemical Abstracts Service Registration Number (CAS No.): 6147-66-6 |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. |
| Hazardous characteristics: / |
| Hazardous combustion products: / |
| Special Fire Fighting Procedures: Firefighters should wear a gas-filled respirator, wear a full-body fire suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Sixth, leakage treatment method
| It is recommended that emergency personnel wear inflatable breathing apparatus, wear anti-static clothing, and wear rubber and oil resistant gloves. Do not touch or cross spills. All equipment used in the work should be grounded. Cut off the source of the leak as much as possible. Eliminate all ignition sources. The warning zone is delineated according to the influence area of liquid flow, steam or dust diffusion, and the unrelated personnel are evacuated from the crosswind and the upwind to the safe zone. |
| Environmental precautions: Contain spills to avoid environmental pollution. Prevent spills from entering sewers, surface water and groundwater. |
Seventh, Handling and storage
| Handling Precautions: Operators should be specially trained to strictly follow the operating procedures. Handling should be carried out in a location with local or full ventilation. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues. Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Storage Precautions: Store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat. Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation. Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation. |
| Eye protection with chemical safety eyes. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Smoking, eating and drinking are prohibited on the job site. After work, take a shower. Maintain good hygiene practices. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Colorless pale yellow aqueous solution or crystalline solid |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | 166-168oC |
| Boiling point (°C) | 115.3oC at 760 mmHg |
| Flash point (°C) | -6 ° C (lit.) |
| Evaporation rate | / |
| Flammability (solid, gaseous) | / |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | / |
| Relative density | / |
| Solubility | / |
| Uses | It is used as a pharmaceutical intermediate, a polymer monomer, and a dyeing assistant monomer for printing and dyeing auxiliaries. |
Tenth, stability and reactivity
| Chemical stability: This product is stable during storage and use at normal ambient temperature. |
| Possibility of dangerous reactions: / |
| Conditions to avoid (such as static unloading, shock or vibration): Electrostatic discharge, heat, humidity, etc. |
| Incompatible materials and materials: Strong oxides, strong acids, strong bases. |
| Dangerous decomposition products: / |
Eleventh, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms related to physical, chemical and toxicological characteristics: acute toxicity |
| Chronic toxicity or long-term toxic effects: / |
| Numerical measure of toxicity (eg acute toxicity estimate): / LD50: / LC50: / |
Twelveth, Ecological information
| Ecotoxicity: / |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Recycle as much as possible.
If it cannot be recycled, it is disposed of by incineration.
Do not dispose of this product by discharging it into the sewer.
Fourteen, Transportation information
| Dangerous Goods Code: UN2376 |
| UN number: 2376 |
| UN transport name: 2,3-DIHYDROPYRAN |
| Transport hazard categories: 3 |
| Packing category: Class II |
| Packing method: Pack according to the manufacturer's recommended method, for example: open steel drum. An ordinary wooden box outside the ampoule. Threaded glass bottles, iron caps, glass bottles, plastic bottles or metal barrels (cans) outside the ordinary wooden box. |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank), the vehicle should have a grounding chain. A hole partition can be installed in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. Part 15 |
Fifteen, Regulatory information
| Applicable Regulations: Regulations on the Safety Management of Chemical Dangerous Goods (promulgated by the State Council on February 17, 1987), Regulations for the Administration of Safety Regulations for Chemical Dangerous Goods (Hua Fafa [1992] No. 677), Regulations on the Safe Use of Chemicals in the Workplace ([1996] Labor Department issued No. 423) and other regulations, for the safe use, production, storage, transportation, loading and unloading of chemical dangerous goods, etc.; the classification and mark of commonly used dangerous chemicals (GB 13690-92) A flash point flammable liquid in Class 3.2. |
Sixteen, Other information
| references | / | |
| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
