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First, the goods and manufacturers information
| Item Name: N-Methyldiallylamine |
| Other names: Methyldiallylamine; N-Methyldiallylamine |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: N-Methyldiallylamine |
| Item Hazard Classification and Country or Region Information: Product Classification: Flammable Liquid Category 2 Skin Corrosion / Stimulation Category 1B |
GHS label elements, including precautionary statements:   Signal words: Hazardous Hazard Statement: Highly flammable liquids and vapours. Causes severe skin burns and eye damage. Prevention : P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. Ground/equal connection of P240 container and loading equipment. P241 Use explosion-proof electrical / ventilation / lighting / equipment. P242 can only use tools that do not produce sparks. P243 Take measures to prevent electrostatic discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection. P260 Do not breathe dust/fume/gas/mist/vapour/spray. P264 Wash thoroughly after work. • Reaction : • P303+P361+P353 If skin (or hair) is contaminated: Take off immediately all contaminated clothing. Wash skin/shower with water. • P370+P378 In case of fire: Use a fire extinguisher to extinguish the fire. • P301+P330+P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting. • P363 contaminated clothing can be reused after cleaning. • P304+P340 IF INHALED: Remove person to fresh air and keep in a position comfortable for breathing. • P310 Call the Detoxification Center/Doctor immediately • P321 Specific treatment (see... on this label). • P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. If you wear contact lenses and can easily remove them, take out the contact lenses. Continue to rinse. • Safe storage: • Store P403+P235 in a well ventilated area. Keep it cool. • The P405 storage area must be locked. Disposal : P501 Dispose of contents/container in accordance with local regulations. |
Third, the component identification data Pure substances:
| Chemical name: N-Methyldiallylamine |
| Common Name: N-Methyldiallylamine |
| Chemical Abstracts Service Registration Number (CAS No.): 2424-01-3 |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. |
| Hazardous characteristics: No information available. |
| Hazardous combustion products: carbon monoxide, carbon dioxide, hydrogen chloride, phosgene. |
| Special Fire Fighting Procedures: Firefighters must wear a filter-type gas mask (full face mask) or an isolated respirator, wear a full-body fire-fighting anti-virus suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or produces sound from a safety relief device, it must be evacuated immediately. |
Sixth, leakage treatment method
| Small amount of leakage: Collect leaking liquid as much as possible in a closable container. Absorb with sand, activated carbon or other inert materials and transfer to a safe place. It is forbidden to rush into the sewer. A large number of leaks: building a dike or digging a pit. Close the drain pipe. Cover with foam to inhibit evaporation. Transfer to a tank truck or special collector with an explosion-proof pump, recycle or transport to a waste disposal site for disposal. |
| Environmental precautions: It is recommended that emergency personnel wear inflatable breathing apparatus, wear anti-static clothing, and wear rubber and oil resistant gloves. Do not touch or cross spills. All equipment used in the work should be grounded. Cut off the source of the leak as much as possible. Eliminate all ignition sources. The warning zone is delineated according to the influence area of liquid flow, steam or dust diffusion, and the unrelated personnel are evacuated from the crosswind and the upwind to the safe zone. |
Seventh, Handling and storage
| Handling Precautions: Operators should be specially trained to strictly follow the operating procedures. Handling should be carried out in a location with local or full ventilation. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues. Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Storage Precautions: Store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat. Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation. Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation. |
| Eye protection: Wear chemical safety eye protection. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Smoking, eating and drinking are prohibited on the job site. After work, take a shower. Maintain good hygiene practices. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Colorless transparent liquid |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | / |
| Boiling point (°C) | 111 °C (lit.) |
| Flash point (°C) | 45 °F |
| Evaporation rate | / |
| Flammability (solid, gaseous) | combustible |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | / |
| Relative density | 0.789 g/mL at 25 °C (lit.) |
| Solubility | / |
| Uses | / N,N-Diallylmethylamine is a very good non-toxic monomer. High-efficiency cationic organic polymer flocculant containing five-membered ring synthesized by homopolymerization and copolymerization due to its high positive charge density It has good water solubility and no pollution. It has a wide range of applications in new inkjet dyes, oil extraction, water treatment and as paper reinforcing agents and antistatic agents. |
Tenth, stability and reactivity
| Chemical stability: This product is stable during storage and use at normal ambient temperature. |
| Possibility of hazardous reactions: There are no known dangerous reactions. |
| Conditions to avoid (such as static unloading, shock or vibration): Electrostatic discharge, heat, humidity, etc. |
| Incompatible materials and materials: / |
| Dangerous decomposition products: / |
Eleventh, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms related to physical, chemical and toxicological characteristics: acute toxicity |
| Chronic toxicity or long-term toxic effects: / |
| Quantitative measures of toxicity (eg acute toxicity estimates): LD50: 823 mg/kg (rat oral); LC50: no data available |
Twelveth, Ecological information
| Ecotoxicity: / |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Refer to national and local regulations before disposal. It is recommended to use incineration. After mixing with the fuel, it is incinerated. The hydrogen halide discharged from the incinerator is removed by an acid scrubber.
Fourteen, Transportation information
| Dangerous Goods Code: / |
| UN number: 2733 |
| UN transport name: AMINES, FLAMMABLE, CORROSIVE, NOS or POLYAMINES, FLAMMABLE, CORROSIVE, NOS |
| Transport hazard categories: 3 |
| Packing category: Class II |
| Packing method: Pack according to the manufacturer's recommended method, for example: open steel drum. An ordinary wooden box outside the ampoule. Threaded glass bottles, iron caps, glass bottles, plastic bottles or metal barrels (cans) outside the ordinary wooden box. |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank), the vehicle should have a grounding chain. A hole partition can be installed in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. |
Fifteen, Regulatory information
| Applicable Regulations: Component Methyldiallylamine CAS: 2424-01-3 People's Republic of China Occupational Disease Prevention Law: occupational hazards Category (2015): not included in the Ordinance on Hazardous Chemical Safety: Dangerous Goods Chemicals Directory (2015): not listed Easy system into the explosion of hazardous chemicals (2017): not included in the key regulatory hazardous chemicals list:List of hazardous chemicals first and second batch of key regulation: not included in the risk management environment registration of chemicals (trial) : focus on environmental management of hazardous chemicals directory: not listed regulations narcotic drugs and Psychotropic drugs: narcotic drugs directory varieties: psychotropic drugs not included in the directory: not included in the new chemical substances environmental Administration: China existing chemical substances ( 2013): included |
Sixteen, Other information
| references | / | |
| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
