First, the goods and manufacturers information
| Item Name: 1,6-Dichlorohexane |
| Other names: 1,6-dichlorohexane; 1,6-dichlorohexane, 97%; 1,6-dichlorohexane; 1,6-dichloro-n-hexane; 1,6-dichlorohexane (hexamethylene dichloride); hexamethylene dichloride; 6-dichlorohexane |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: 1,6-Dichlorohexane |
| Hazard classification and national or regional information: Product classification: Inhalation hazard category 1; Skin corrosion/irritation category 2; Hazardous aquatic environment - Long-term hazard category 2 |
GHS label elements, including precautionary statements:    Signal word: Hazardous Hazard Statement: H304 May be fatal if swallowed and enters the respiratory tract. H315 Causes skin irritation. H411 is toxic to aquatic life with long lasting effects. Prevention : P264 Wash thoroughly after work. • P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. • P273 Avoid release to the environment. Response : P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor • P331 Do not induce vomiting. • P302+P352 IF ON SKIN: Wash thoroughly with water. • P321 specific treatment (see ... on this label). • P332+P313 If skin irritation occurs: Get medical advice/ attention. • P362+P364 Take off contaminated clothing and wash it before reuse. • P391 Collect spillage. Storage : P405 Storage must be locked. Disposal : P501 Dispose of contents/container in accordance with local regulations. |
Third, the component identification data Pure substances:
| Chemical name: 1,6-Dichlorohexane / |
| Common name: 1,6-Dichlorohexane |
| Chemical Abstracts Service Registration Number (CAS No.): 2163-00-0 |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protective measures for emergency personnel: / Emergency personnel should wear a gas-filled respirator, wear an anti-static suit, and wear rubber-resistant gloves. |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. |
| Hazardous characteristics: / |
| Hazardous combustion products: carbon monoxide, carbon dioxide, hydrogen chloride, phosgene. |
| Special Fire Fighting Procedures: Firefighters should wear a gas-filled respirator, wear a full-body fire suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Sixth, leakage treatment method
| Personal precautions, protective equipment and emergency procedures: Rapid evacuation of personnel from the contaminated area to a safe area, isolation and strict restrictions on access. Cut off the fire source. It is recommended that emergency personnel wear self-contained positive pressure breathing apparatus and wear anti-virus suits. Cut off the leak source as much as possible and do not directly touch the leak. Contain spills to avoid polluting the environment. Prevent spills from entering sewers, surface water and groundwater. |
| Environmental precautions: Contain spills to avoid environmental pollution. Prevent spills from entering sewers, surface water and groundwater. |
Seventh, Handling and storage
| Handling Precautions: Operators should be specially trained to strictly follow the operating procedures. Handling should be carried out in a location with local or full ventilation. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues. Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Storage Precautions: Store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat. Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation. Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation. |
| Eye protection: Wear chemical safety eye protection. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Smoking, eating and drinking are prohibited on the job site. After work, take a shower. Maintain good hygiene practices. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Transparent, colorless liquid. |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | -13 °C |
| Boiling point (°C) | 87 °C |
| Flash point (°C) | 74 ° C (lit.) |
| Evaporation rate | / |
| Flammability (solid, gaseous) | / |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | / |
| Relative density | 1.068 g/mL at 25 °C (lit.) |
| Solubility | Water soluble: sparingly soluble |
| Uses | The intermediate used in the manufacture of pesticides is also a raw material for organic synthesis. |
Tenth, stability and reactivity
| Chemical stability: Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. |
| Possibility of hazardous reactions: There are no known dangerous reactions. |
| Conditions to avoid (such as static unloading, shock or vibration): Electrostatic discharge, heat and humidity, etc. Electrostatic discharge, heat, humidity, etc., electrostatic discharge, heat, humidity, etc. Electrostatic discharge, heat, humidity, etc. |
| Incompatible materials and materials: Strong oxides, strong acids, strong bases. |
| Dangerous decomposition products: / |
Eleventh, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms about physical, chemical and toxicological characteristics: / |
| Chronic toxicity or long-term toxic effects: / |
| Numerical measure of toxicity (eg acute toxicity estimate): LD50: no data LC50: no data available |
Twelveth, Ecological information
| Ecotoxicity: / |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Recycle as much as possible. If it cannot be recycled, it is disposed of by incineration. Do not dispose of this product by discharging it into the sewer. Return the container to the manufacturer or dispose of it in accordance with national and local regulations. Refer to national and local regulations before disposal. See Section 8 for safety precautions for disposers.
Fourteen, Transportation information
| Dangerous Goods Code: UN3082 |
| UN number: 3082 |
| UN transport name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, NOS |
| Transport hazard categories: 9 |
| Packing category: Class III |
| Packing method: Pack according to the manufacturer's recommended method, for example: open steel drum. An ordinary wooden box outside the ampoule. Threaded glass bottles, iron caps, glass bottles, plastic bottles or metal barrels (cans) outside the ordinary wooden box. |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank), the vehicle should have a grounding chain. A hole partition can be installed in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. |
Fifteen, Regulatory information
| Applicable Regulations: Regulations on the Safety Management of Chemical Dangerous Goods (promulgated by the State Council on February 17, 1987), Regulations for the Administration of Safety Regulations for Chemical Dangerous Goods (Hua Fafa [1992] No. 677), Regulations on the Safe Use of Chemicals in the Workplace ([1996] Labor Department issued No. 423) and other regulations, for the safe use, production, storage, transportation, loading and unloading of chemical dangerous goods, etc.; the classification and mark of commonly used dangerous chemicals (GB 13690-92) A flash point flammable liquid in Class 3.2. |
Sixteen, Other information
| references | [1] International Chemical Safety Programme: International Chemical Safety Card (ICSC), available at http://www.ilo.org/dyn/icsc/showcard.home. [ 2 ] International Agency for Research on Cancer, http://www.iarc.fr/. [ 3 ] OECD Global Chemical Information Platform at http://www.echemportal.org/echemportal/index pageID=0&request_locale=en . [4] US CAMEO Chemical Substance Database, http://cameochemicals.noaa.gov/search/simple. [5] American Medical Library: Chemical Identification Database, http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp. [6] US Environmental Protection Agency: Comprehensive Risk Information System at http://cfpub.epa.gov/iris/. [7] US Department of Transportation: Emergency Response Guide, available at http://www.phmsa.dot.gov/hazmat/library/erg. [8] German GESTIS-Hazardous Substance Database, http://gestis-en.itrust.de/. |
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| Tabulation unit |
Name: Zouping Qili Additives Co., Ltd. | |
| Address / Tel: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China /0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
