First, the goods and manufacturers information
| Item Name: Acetylacetone |
| Other names: diacetylmethane; m-pentanedione; acetylpropyl copper; acetylacetone; 2,4-pentanedione, 99%; diacetylmethane, 2,4-pentanedione; 2,4- Acetylacetone |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: Acetylacetone |
| Hazard classification and national or regional information: Product classification: Flammable liquid category 3; Acute oral toxicity category 4 |
GHS label elements, including precautionary statements:   Signal word: Warning Hazard statement: H226 Flammable liquid and vapour. H302 Harmful if swallowed. Prevention : P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. • P233 Keep container tightly closed. • Ground/equal connection of P240 container and loading equipment. • P241 uses explosion-proof electrical / ventilation / lighting / equipment. • P242 can only use tools that do not produce sparks. • P243 Take measures to prevent electrostatic discharge. • P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. • P264 is thoroughly cleaned after work. • P270 Do not eat, drink or smoke when using this product. Reaction : P303+P361+P353 Skin (or hair) Contamination: Take off immediately all contaminated clothing. Wash skin / shower with water. • P370+P378 In case of fire: Use a fire extinguisher to extinguish the fire. • P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell • P330 gargle. Storage : P403+P235 Store in a well-ventilated place. Keep it cool. Disposal : P501 Dispose of contents/container in accordance with local regulations. |
Third, the component identification data Pure substances:
| Chemical name: Acetylacetone / |
| Common Name: Acetylacetone |
| Chemical Abstracts Service Registration Number (CAS No.): 123-54-6 |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protective measures for emergency personnel: / Emergency personnel should wear a gas-filled respirator, wear an anti-static suit, and wear rubber-resistant gloves. |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. |
| Hazardous characteristics: / |
| Hazardous combustion products: carbon monoxide, carbon dioxide, hydrogen chloride, phosgene. |
| Special Fire Fighting Procedures: Firefighters should wear a gas-filled respirator, wear a full-body fire suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Sixth, leakage treatment method
| Personal precautions, protective equipment and emergency procedures: It is recommended that emergency personnel wear inflatable breathing apparatus, antistatic clothing and rubber and oil resistant gloves. Do not touch or cross spills. All equipment used in the work should be grounded. Cut off the source of the leak as much as possible. Eliminate all ignition sources. The warning zone is delineated according to the influence area of liquid flow, steam or dust diffusion, and the unrelated personnel are evacuated from the crosswind and upwind to the safe zone. |
| Environmental precautions: Contain spills to avoid environmental pollution. Prevent spills from entering sewers, surface water and groundwater. |
Seventh, Handling and storage
| Handling Precautions: Operators should be specially trained to strictly follow the operating procedures. Handling should be carried out in a location with local or full ventilation. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues. Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Storage Precautions: Store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat. Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation. Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation |
| Eye protection: Wear chemical safety eye protection. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Smoking, eating and drinking are prohibited on the job site. After work, take a shower. Maintain good hygiene practices. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Colorless or yellow liquid |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | -23 °C |
| Boiling point (°C) | 140.4 °C |
| Flash point (°C) | 34°C |
| Evaporation rate | / |
| Flammability (solid, gaseous) | / |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | / |
| Relative density | 0.975 g/mL at 25 °C (lit.) |
| Solubility | Water solubility: 16 g / 100 mL (20 oC). |
| Uses | The intermediate used in the manufacture of pesticides is also a raw material for organic synthesis. |
Tenth, stability and reactivity
| Chemical stability: Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. Stored and used under normal ambient temperature, this product is stable. |
| Possibility of hazardous reactions: There are no known dangerous reactions. |
| Conditions to avoid (such as static unloading, shock or vibration): Electrostatic discharge, heat and humidity, etc. Electrostatic discharge, heat, humidity, etc., electrostatic discharge, heat, humidity, etc. Electrostatic discharge, heat, humidity, etc. |
| Incompatible materials and materials: Strong oxides, strong acids, strong bases. |
| Dangerous decomposition products: / |
Eleventh, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms about physical, chemical and toxicological characteristics: / |
| Chronic toxicity or long-term toxic effects: / |
Quantitative measures of toxicity (eg acute toxicity estimates): Oral: LD50 Rat (male) oral 760 mg/kg Inhalation: LC50 Rat inhalation 1224 ppm/4 hr (5.1 mg/L/4 hr) Percutaneous: LD50 Rabbit percutaneous 810 mg/kg |
Twelveth, Ecological information
| Ecotoxicity: / Acute toxicity test for fish: LC50 Pimephales promelas (fathead minnow) 200 mg/L/24 hr /Conditions of bioassay not specified in source Refer to acute toxicity inhibition test: EC50 Daphnia magna (water flea) 75 mg/ L/48 hr; Effect: mortality or immobility; closed static bioassay, total hardness (CaCO3) 240 mg/L, pH 8.0 + or - 0.3, aerated (before use), carbon-filtered well water, 23°C, 16 hr Photoperiod ... /Reagent grade |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Recycle as much as possible. If it cannot be recycled, it is disposed of by incineration. Do not dispose of this product by discharging it into the sewer. Return the container to the manufacturer or dispose of it in accordance with national and local regulations. Refer to national and local regulations before disposal. See Section 8 for safety precautions for disposers.
Fourteen, Transportation information
| Dangerous Goods Code: UN 2310 |
| UN number: 2310 |
| UN transport name: PENTANE-2, 4-DIONE PENTANE-2, 4-DIONE PENTANE-2, 4-DIONE PENTANE-2, 4-DIONE |
| Transport hazard category: 6.1 |
| Packing category: Class III |
| Packing method: Pack according to the manufacturer's recommended method, for example: open steel drum. An ordinary wooden box outside the ampoule. Threaded glass bottles, iron caps, glass bottles, plastic bottles or metal barrels (cans) outside the ordinary wooden box. |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank), the vehicle should have a grounding chain. A hole partition can be installed in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. |
Fifteen, Regulatory information
| Applicable Regulations: Occupational Disease Prevention Law of the People's Republic of China: Classification of Occupational Disease Hazard Factors (2015): Not listed in the Hazardous Chemicals Safety Management Regulations: Dangerous Chemicals List (2015): Listed ; Easy to Explode Hazardous Chemicals List (2017) : List of hazardous chemicals not listed for priority supervision: List of first and second batches of keyly regulated hazardous chemicals: Not included in the Environmental Management Registration Procedure for Hazardous Chemicals (Trial): List of hazardous environmental management hazardous chemicals: No included in the regulations narcotic drugs and Psychotropic drugs: narcotic drugs directory varieties: not included ; psychotropic drugs directory: not included in the new chemical substances environmental Administration: China Inventory of existing chemical substances in China (2013): inclusion |
Sixteen, Other information
| references | [1] International Chemical Safety Programme: International Chemical Safety Card (ICSC), available at http://www.ilo.org/dyn/icsc/showcard.home. [ 2 ] International Agency for Research on Cancer, http://www.iarc.fr/. [ 3 ] OECD Global Chemical Information Platform at http://www.echemportal.org/echemportal/index pageID=0&request_locale=en . [4] US CAMEO Chemical Substance Database, http://cameochemicals.noaa.gov/search/simple. [5] American Medical Library: Chemical Identification Database, http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp. [6] US Environmental Protection Agency: Comprehensive Risk Information System at http://cfpub.epa.gov/iris/. [7] US Department of Transportation: Emergency Response Guide, available at http://www.phmsa.dot.gov/hazmat/library/erg. [8] German GESTIS-Hazardous Substance Database, http://gestis-en.itrust.de/. |
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| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
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Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 |
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| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
