First, the goods and manufacturers information
| Item Name: 3-Chloro-1-propanol |
| Other names: Propionyl chloride |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: 3-Chloro-1-propanol |
| Hazard classification and national or regional information: Product classification: Flash point flammable liquid in category 3.2 |
GHS label elements, including precautionary statements:  Signal word: Hazard and danger Description: / Prevention : / Reaction : Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. Ingestion: Ingestion, vomiting is prohibited. Seek medical attention immediately. Inhalation: If inhaled, move the patient to fresh air. Enter the eye: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. Storage : Store in a cool, ventilated warehouse. Temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat.Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks.The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. Disposal : Refer to national and local regulations before disposal. It is recommended to use incineration. After mixing with the fuel, it is incinerated. The hydrogen halide discharged from the incinerator is removed by an acid scrubber. |
Third, the component identification data
Pure substances:
| Chemical name: 3-Chloro-1-propanol / |
| Common name: / |
| Chemical Abstracts Service Registration Number (CAS No.): 627-30-5 |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. |
| Hazardous characteristics: No information available. |
| Hazardous combustion products: / |
| Special Fire Fighting Procedures: Firefighters should wear a gas-filled respirator, wear a full-body fire suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Sixth, leakage treatment method
| Personal precautions, protective equipment and emergency procedures: Rapid evacuation of personnel from the contaminated area to a safe area, isolation and strict restrictions on access. Cut off the fire source. It is recommended that emergency personnel wear self-contained positive pressure breathing apparatus and wear anti-virus suits. Cut off the leak source as much as possible and do not directly touch the leak. Prevent entry into restricted spaces such as sewers and row drains. |
| Environmental precautions: / Cleaning methods and materials: Small spills: Mix with sand, dry lime or soda ash. A large number of leaks: building a dike or digging a pit. Transfer to a tank truck or special collector with a pump, recycle or transport to a waste disposal site for disposal. |
Seventh, Handling and storage
| Handling precautions: Closed operation to provide adequate local exhaust. Operators must be specially trained to strictly follow the operating procedures. Operators are advised to wear self-priming filter respirators (full face masks), tape anti-drugs, and rubber-resistant gloves. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. Avoid generating smoke. Prevent smoke and vapors from being released into the workplace air. Avoid contact with oxidants, alcohols, and alkalis. Pay particular attention to avoid contact with water. Lightly load and unload during handling to prevent damage to packaging and containers. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. Empty containers may be harmful residues. |
| Storage Precautions: Store in a cool, ventilated warehouse. Keep away from fire and heat. The temperature of the reservoir should not exceed 30 °C. Keep the container sealed. It should be stored separately from oxidants, reducing agents, acids, alkalis, and food chemicals. Avoid mixing.Explosion-proof lighting and ventilation facilities are used. It is forbidden to use mechanical equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering control: Strictly closed, providing sufficient local exhaust. As mechanized and automated as possible. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Self-priming filter respirators (full face masks) should be worn when exposed to vapors. Wear an oxygen breathing apparatus during emergency rescue or evacuation |
| Eye protection: Protected from respiratory system protection. |
| Skin and body protection: Wear tape anti-virus clothing. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Smoking, eating and drinking are prohibited on the job site. After work, take a shower. Maintain good hygiene practices. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Colorless to pale yellow liquid. |
| odor | Strong irritating odor. |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | -94/ |
| Boiling point (°C) | 80 |
| Flash point (°C) | 12 |
| Evaporation rate | / |
| Flammability (solid, gaseous) | combustible |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | 3.2 (relative vapour density, air = 1) |
| Relative density | 1.06 (water = 1) |
| Solubility | Soluble in water and ethanol. |
| Uses | The intermediate used in the manufacture of pesticides is also a raw material for organic synthesis. |
Tenth, stability and reactivity
| Chemical stability: stable at room temperature. |
| Possibility of hazardous reactions: There are no known dangerous reactions. |
| Conditions to avoid (such as static unloading, shock or vibration): fire, heat source. |
| Incompatible materials and materials: oxidizing agents, reducing agents, acids, alkalis, food chemicals |
| Hazardous decomposition products: carbon monoxide, carbon dioxide, hydrogen chloride. |
Eleventh, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms related to physical, chemical and toxicological characteristics: acute toxicity |
| Chronic toxicity or long-term toxic effects: / |
| Quantitative measures of toxicity (eg acute toxicity estimates): LD50: 823 mg/kg (rat oral); LC50: no data available |
Twelveth, Ecological information
| Ecotoxicity: / |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Refer to national and local regulations before disposal. It is recommended to use incineration. After mixing with the fuel, it is incinerated. The hydrogen halide discharged from the incinerator is removed by an acid scrubber.
Fourteen, Transportation information
| Dangerous Goods Code: 61584 |
| UN number: 2849 |
| UN transport name: 3-CHLORO-PROPANOL-1 |
| Transport hazard categories: 6.1 |
| Packing category: III |
| Packing method: Pack according to the manufacturer's recommended method, for example: open steel drum. An ordinary wooden box outside the ampoule. Threaded glass bottles, iron caps, glass bottles, plastic bottles or metal barrels (cans) outside the ordinary wooden box. |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank) vehicle, there should be a grounding chain. A hole partition can be provided in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. |
Fifteen, Regulatory information
| Applicable regulations: Component 3-Chloro-1-propanol CAS: 627-30-5 Occupational Disease Prevention Law of the People's Republic of China: Classification of Occupational Disease Hazard Factors (2015): Not listed in the Hazardous Chemicals Safety Management Regulations: Dangerous Chemicals List (2015): List of Hazardous Chemicals Listed in Explosives (2017): List of Hazardous Chemicals Not Listed in Key Regulations: First and Second Batch of Listed Hazardous Chemicals Listed: Not included in Environmental Management of Hazardous Chemicals Registration Method (Trial): List of Hazardous Chemicals for Key Environmental Management: Regulations for the Administration of Narcotic Drugs and Psychotropic Substances: Catalogue of Narcotic Drugs: Not listed in the list of psychotropic substances: Environmental management measures not included in new chemical substances: China Directory of Chemical Substances (2013): Inclusion. |
Sixteen, Other information
| references | / | |
| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
