First, the goods and manufacturers information
| Item Name: Dichlormid |
| Other names: N, N- diallyl-2,2-dichloroacetamide; N, N- hexadiene dichloroacetamide |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: Diallylamine |
| Item Hazard Classification and Country or Region Information: Product Classification: Skin Corrosion / Stimulus Category 2 |
Global Harmonized System label elements, including precautionary statements:  Signal words: Hazardous Hazard Description: Flammable, toxic, can cause skin burns, and is highly irritating. Prevention : P264 Wash thoroughly after work. P280 Wear protective gloves / protective clothing / Wear protective goggles / wear protective masks. Reaction : P302+P352 IF ON SKIN: Wash thoroughly with water. • P321 specific treatment (see ... on this label). • P332+P313 If skin irritation occurs: Get medical advice/ attention. • P362+P364 Take off contaminated clothing and wash it before reuse. Storage : None |
Third, the component identification data Pure substances:
| Chemical name: Dichlormid |
| Common name: / |
| Chemical Abstracts Service Registration Number (CAS No.): / |
| Hazardous substance composition (percentage of ingredients): >99% |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. |
| Hazardous characteristics: No data available |
| Hazardous combustion products: |
| Special Fire Fighting Procedures: Firefighters should wear a gas-filled respirator, wear a full-body fire suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Sixth, leakage treatment method
| It is recommended that emergency personnel wear inflatable breathing apparatus, wear anti-static clothing, and wear rubber and oil resistant gloves. Do not touch or cross spills. All equipment used in the work should be grounded. Cut off the source of the leak as much as possible. Eliminate all ignition sources. The warning zone is delineated according to the influence area of liquid flow, steam or dust diffusion, and the unrelated personnel are evacuated from the crosswind and the upwind to the safe zone. |
| Environmental precautions: Contain spills to avoid environmental pollution. Prevent spills from entering sewers, surface water and groundwater. |
Seventh, Handling and storage
| Operators should be specially trained to strictly follow the operating procedures. The handling should be local. Conducted in a wind or full ventilation facility. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues.Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat.Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks.The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation.Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation. |
| Eye protection: Wear chemical safety eye protection. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: / |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Yellow transparent liquid |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | 5.0-6.5 °C |
| Boiling point (°C) | 118 °C / 2mmHg |
| Flash point (°C) | 106 ° C (lit.) |
| Evaporation rate | / |
| Flammability (solid, gaseous) | |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | / |
| Vapor density | / |
| Relative density | 1.192-1.204 |
| Solubility | / |
| Uses | / |
Tenth, stability and reactivity
| Chemical stability: |
| Possibility of dangerous reactions: |
| Conditions to avoid (such as static unloading, shock or vibration): |
| Incompatible materials and materials: / |
| Dangerous decomposition products: / |
Eleventh, Toxic information
| Exposure route: |
| Symptoms about physical, chemical and toxicological characteristics: |
| Chronic toxicity or long-term toxic effects: / |
| Numerical measure of toxicity (eg acute toxicity estimates): |
Twelveth, Ecological information
| Ecotoxicity: / |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods : Refer to national and local regulations before disposal. It is recommended to use incineration. The nitrogen oxides emitted from the incinerator are removed by a scrubber.
Fourteen, Transportation information
| Dangerous Goods Code: 321 79 |
| UN number: 2359 |
| UN transport name: diallylamine |
| Transport hazard categories: |
| Packing category: O52 |
| Packing method: ordinary wooden box outside the ampoule; threaded glass bottle, iron cover glass bottle, plastic bottle or metal barrel (can) outside the ordinary wooden box |
| Transportation precautions: Transportation vehicles should be equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is best to transport in the summer and evening. The tank (tank) used in transportation should have a grounding chain, and a hole partition can be arranged in the tank to reduce the static electricity generated by the shock. It is strictly forbidden to mix and transport with oxidants, acids, food chemicals, etc. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. The vehicle exhaust pipe carrying the item must be equipped with a fire-stop device, and it is forbidden to use the mechanical equipment and tools that are prone to sparks. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail.It is strictly forbidden to transport in bulk by wooden or cement vessels. |
Fifteen, Regulatory information
| Occupational Disease Prevention Law of the People's Republic of China: Classification of Occupational Disease Hazard Factors (2015): Not listed in the Hazardous Chemicals Safety Management Regulations: Dangerous Chemicals List (2015): Not included in the list of explosive chemicals (2017): Not List of Hazardous Chemicals Listed in Key Regulations: List of the first and second batches of keyly regulated hazardous chemicals: Not included in the Environmental Management Registration Procedure for Hazardous Chemicals (Trial): Key Environmental Management Hazardous Chemicals Directory: Not included in anesthesia Regulations on the Administration of Pharmaceuticals and Psychotropic Substances: Catalogue of Narcotic Drugs: Not included in the list of psychotropic substances: Environmental management measures not included in new chemical substances: List of existing chemical substances in China (2013): Not included |
Sixteen, Other information
| references | / | |
| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
