First, the goods and manufacturers information
| Item Name: 3-Allyl chloride |
| Other names: Allyl chloride |
| Suggestions for use and usage restrictions: / |
| Manufacturer or supplier name, address and telephone number: /Zouping Qili Additives Co., Ltd. Houcheng Village, Daixi Office, Zouping County, Shandong Province, China |
| Emergency contact number / fax number: 4780006/0543-4537355 |
Second, the danger mark
| Item Name: 3-Allyl chloride |
| Hazard classification and national or regional information: Product classification: Flammable liquid Category 2 Acute oral toxicity Category 4 Acute dermal toxicity Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Acute inhalation toxicity Category 4 Specific Target Organs Toxicity Primary Contact Category 3 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 2 Specific Target Organ Toxicity Repeated Exposure Category 2 Hazardous Aquatic Environment - Acute Hazard Category 1 |
GHS label elements, including precautionary statements:     Signal word: Hazardous Hazard Statement: H225 Highly flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 can cause respiratory irritation. H341 suspected of causing genetic defects. H351 suspected of causing cancer. H400 extremely toxic to aquatic organisms Prevention : P210 away from heat / sparks / open flames / hot surfaces. No smoking. P233 Keep container tightly closed. Ground/equal connection of P240 container and loading equipment. P241 Use explosion-proof electrical / ventilation / lighting / equipment. P242 can only use tools that do not produce sparks. P243 Take measures to prevent electrostatic discharge. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P264 Wash thoroughly after work. P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapor/spray. P271 can only be used outdoors or in a well ventilated area. P201 Obtain special instructions before use. P202 Do not move until all safety measures have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapor/spray. P273 Avoid release to the environment. Reaction : Skin contact: Take off immediately all contaminated clothing. Wash skin / shower with water. Ingestion: If you feel unwell, call the Detoxification Center / Doctors inhalation: Quickly leave the site to fresh air. Keep the airway open. If breathing is difficult, give oxygen. If breathing stops, perform artificial respiration immediately. Seek medical attention. Enter your eyes: Rinse cautiously with water for a few minutes. If you wear contact lenses and can easily remove them, take out the contact lenses. Continue to rinse, seek medical advice / see a doctor. Storage : P403+P235 Store in a well-ventilated place. Keep it cool. P403+P233 Store in a well ventilated area. Keep the container closed. The P405 storage area must be locked. Disposal : Refer to national and local regulations before disposal. |
Third, the component identification data
Pure substances:
| Chemical name: 3-Allyl chloride |
| Common name: / |
| Chemical Abstracts Service Registration Number (CAS No.): 107-0501 |
| Hazardous substance composition (% of composition): 100 % |
Mixture:
| Chemical properties: / |
| Hazardous substance composition: / |
| Concentration or concentration range (percentage of ingredients): / |
Fourth, first aid measures
| First aid methods for different exposure routes: / |
| Inhalation: If inhaled, move the patient to fresh air. |
| Skin contact: Remove contaminated clothing and wash skin thoroughly with soap and water. Get medical attention if you feel uncomfortable. |
| Eye contact: Separate the eyelids and rinse with running water or saline. Seek medical attention immediately. |
| Ingestion: Rinse mouth, no vomiting. Seek medical attention immediately. |
| The most important symptoms and dangerous effects: / |
| Protection that emergency personnel should take: / |
| Indication of immediate medical attention and special treatment needed if necessary: / |
Fifith, Fire fighting measures
| Extinguishing media: Extinguish with water spray, dry powder, foam or carbon dioxide. Avoid using DC water to extinguish the fire. Direct current water may cause splashing of flammable liquids and spread the fire. |
| Hazardous characteristics: Highly flammable liquid and vapour. |
| Hazardous combustion products: / |
| Special Fire Fighting Procedures: Firefighters should wear a gas-filled respirator, wear a full-body fire suit, and extinguish the fire in the upwind direction. Move the container from the fire to the open space as much as possible. If the container in the fire has changed color or sounded from a safe pressure relief device, it must be evacuated immediately. Isolation of the accident site, prohibiting unrelated personnel from entering. Contain and handle fire water to prevent environmental pollution. |
Sixth, leakage treatment method
| It is recommended that emergency personnel wear inflatable breathing apparatus, wear anti-static clothing, and wear rubber and oil resistant gloves. Do not touch or cross spills. All equipment used in the work should be grounded. Cut off the source of the leak as much as possible. Eliminate all ignition sources. The warning zone is delineated according to the influence area of liquid flow, steam or dust diffusion, and the unrelated personnel are evacuated from the crosswind and the upwind to the safe zone. |
| Environmental precautions: Contain spills to avoid environmental pollution. Prevent spills from entering sewers, surface water and groundwater.Small amount of leakage: Collect leaking liquid as much as possible in a closable container. Absorb with sand, activated carbon or other inert materials and transfer to a safe place. It is forbidden to rush into the sewer. A large number of leaks: building a dike or digging a pit. Close the drain pipe. Cover with foam to inhibit evaporation. Transfer to a tank truck or special collector with an explosion-proof pump, recycle or transport to a waste disposal site for disposal. |
Seventh, Handling and storage
| Handling Precautions: Operators should be specially trained to strictly follow the operating procedures. Handling should be carried out in a location with local or full ventilation. Avoid eye and skin contact and avoid inhaling steam. See Section 8 for personal protection measures. Keep away from fire, heat, and smoking in the workplace. Use explosion-proof ventilation systems and equipment. For canning, the flow rate should be controlled and grounded to prevent static buildup. Avoid contact with incompatible materials such as oxidizing agents (see Section 10 for incompatible materials). Lightly load and unload during handling to prevent damage to packaging and containers. Empty containers may be harmful residues. Wash hands after use and prohibit eating in the workplace. Equipped with the corresponding variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. |
| Storage Precautions: Store in a cool, ventilated warehouse. The temperature should not exceed 37 °C. It should be stored separately from oxidants and food chemicals, and should not be mixed (see Section 10 for incompatible materials). Keep the container sealed. Keep away from fire and heat. Lightning protection equipment must be installed in the warehouse. The exhaust system should be provided with a grounding device that removes static electricity. Explosion-proof lighting and ventilation settings. It is forbidden to use equipment and tools that are prone to sparks. The storage area should be equipped with leakage emergency treatment equipment and suitable containment materials. |
Eighth, contact control / personal protection
| Engineering Control: Workplace recommendations are separate from other work sites. Closed operation to prevent leakage. Increase ventilation. Set up automatic alarms and accident ventilation. Set up emergency evacuation routes and necessary quarantine areas. Set the red area warning line, warning sign and Chinese warning instructions, and set the communication alarm system. Safety showers and eyewash equipment are provided. |
| Respiratory protection: Wear a filter-type gas mask (half mask) when the concentration in the air exceeds the standard. Air-operated respirators should be worn during emergency rescue or evacuation. |
| Eye protection: Wear chemical safety eye protection. |
| Skin and body protection: Wear protective clothing to penetrate the overalls. |
| Hand protection: Wear rubber and oil resistant gloves. |
| Other protection: Smoking, eating and drinking are prohibited on the job site. After work, take a shower. Maintain good hygiene practices. |
Ninth, Physical and chemical properties
| Appearance (physical status, color, etc.) | Transparent liquid |
| odor | / |
| Odour devaluation | / |
| pH value | / |
| Melting point / freezing point | -136 °C |
| Boiling point (°C) | 44-46 °C (lit.) |
| Flash point (°C) | - 29°C (lit.) |
| Evaporation rate | / |
| Flammability (solid, gaseous) | / |
| Upper and lower flammability limits or explosion limits | / |
| Vapor pressure (kPa) | 417mmHg at 25°C |
| Vapor density | 2.6 (vs air) |
| Relative density | 0.939 g/mL at 25 °C (lit.) |
| Solubility | Water solubility: 3.6 G/L (20 oC). |
| Uses | The intermediate used in the manufacture of pesticides is also a raw material for organic synthesis. |
Tenth, stability and reactivity
| Chemical stability: This product is stable during storage and use at normal ambient temperature. |
| Possibility of hazardous reactions: There are no known dangerous reactions. |
| Conditions to avoid (such as static unloading, shock or vibration): Electrostatic discharge, heat, humidity, etc. |
| Incompatible materials and materials: Strong oxides, strong acids, strong bases |
| Hazardous decomposition products: carbon monoxide, carbon dioxide, hydrogen chloride |
Eleventh, Toxic information
| Routes of exposure: inhalation, ingestion, eye contact, skin contact. |
| Symptoms about physical, chemical and toxicological characteristics: / |
| Chronic toxicity or long-term toxic effects: / |
| Quantitative measurement of toxicity (eg acute toxicity estimate): Oral: LD50 Mouse oral 425 mg/kg Inhalation: LC50 Mouse inhalation 11,500 mg/cu m/2 hr Percutaneous: Not available |
Twelveth, Ecological information
| Ecotoxicity: / Acute toxicity test for fish: LC50 Lepomis macrochirus (Bluegill) 59.3 mg/L/24 hr (95% confidence interval: 50.87-70.34 mg/L); static /formulated product : Acute activity inhibition test: LC50 Daphnia Magna (Waterflea) 250 mg/L/24 hr; static /formulated product Algae growth inhibition test: No information available. Toxicity to microorganisms: No information available. |
| Persistence and degradability: / |
| Bioaccumulation: / |
| Mobility in the soil: / |
| Other adverse effects: / |
Thirteen, Disposal methods :
Waste chemicals:
recycle as much as possible.
If it cannot be recycled, it is disposed of by incineration.
Do not dispose of this product by discharging it into the sewer.
Contaminated packaging:
return the container to the manufacturer or dispose of it in accordance with national and local regulations.
Disposal considerations:
Refer to national and local regulations before disposal.
See Section 8 for safety precautions for disposers.
Fourteen, Transportation information
| Dangerous Goods Code: 31021 |
| UN number: UN1100 |
| UN shipping name: ALLYL CHLORIDE |
| Transport hazard categories: Flash point flammable liquids in Class 3.2. |
| Packing category: Class I |
| Packing method: Pack according to the manufacturer's recommended method, for example: open steel drum. An ordinary wooden box outside the ampoule. Threaded glass bottles, iron caps, glass bottles, plastic bottles or metal barrels (cans) outside the ordinary wooden box. |
| Transportation precautions: Transportation vehicles should be equipped with the appropriate variety and quantity of fire-fighting equipment and leakage emergency treatment equipment. It is strictly forbidden to mix and transport with oxidants and food chemicals. The vehicle exhaust pipe carrying the item must be equipped with a fire arresting device. When using a tank (tank), the vehicle should have a grounding chain. A hole partition can be installed in the tank to reduce the static electricity generated by the shock. It is forbidden to use mechanical equipment and tools that are prone to sparks. It is best to transport in the summer and evening. During transportation, it should be protected from exposure, rain and high temperature. Keep away from fire, heat and high temperature areas during stopovers. When transporting by road, follow the prescribed route and do not stay in residential areas and densely populated areas. It is forbidden to slip when transporting by rail. It is strictly forbidden to transport in bulk by wooden or cement vessels. Hazard signs and notices shall be posted on the means of transport in accordance with the relevant transport requirements. |
Fifteen, Regulatory information
| Applicable regulations: The following laws, regulations, rules and standards, the corresponding management of the chemical: Component Allyl chloride CAS: 107-05-1 People's Republic of China Occupational Disease Prevention Law: Classification of occupational hazards (2015): Listed in the Hazardous Chemicals Safety Management Regulations: Catalogue of Dangerous Chemicals (2015) : List of Dangerous Chemicals Listed in Explosives (2017) : List of Hazardous Chemicals Not Listed in Key Regulations: First and Second Batch of Key Regulations List of Hazardous Chemicals: Not included in the Environmental Management Registration Procedure for Hazardous Chemicals (Trial): List of Hazardous Chemicals for Key Environmental Management: Not included in the Regulations on the Administration of Narcotic Drugs and Psychotropic Substances: Catalogue of Narcotic Drugs: Not included in Psychotropic Drugs Table of Contents: Environmental Management Measures for New Chemical Substances: List of Existing Chemical Substances in China (2013): |
Sixteen, Other information
| references | / | |
| Tabulation unit | Name: Zouping Qili Additives Co., Ltd. | |
| Address / Phone: Houcheng Village, Daixi Office, Zouping County, Shandong Province, China/0543-4788006 | ||
| Lister / | job title: | Name (signature): / |
| Tabulation date / | / | |
Note 1: When the product is a mixture containing two or more dangerous substances, a safety data sheet should be prepared according to the danger after mixing.
Note 2: The manufacturer/supplier should ensure the correctness of the information contained in the SDS according to the actual situation and update it as appropriate.
Note 3: If there is no information due to product characteristics (such as the absence of boiling point in the solid), it should be marked with "/" in the table.
